Reactivity: the ease with which a chemical substance takes part in a chemical reaction
Reactivity series (of metals): an order of reactivity, giving the most reactive metal first, based on results from a range of experiments involving metals reacting with oxygen, water, dilute hydrochloric acid and metal salt solutions
Establishing the basis of a reactivity series
Reactions with water
From most reactive to least reactive:
Potassium, sodium, calcium, magnesium, aluminium, zinc, iron, copper, silver, gold
Reactions with dilute acids
magnesium
strong reaction, bubbles of gas, magnesium disappears, colourless solution formed
Mg(s) + 2HCl(aq) → MgCl2(aq) + H2(g)
Mg(s) + H2SO4(aq) → MgSO4(aq) + H2(g)
aluminium
slow to react in cold, but bubbles form on heating, aluminium disappears, colourless solution formed
2Al(s) + 6HCl(aq) → 2AlCl3(aq) + 3Н2(g)
2Al(s) + 3H2SO4(aq) → Al2(SO4)3(aq) + 3Н2(g)
zinc
bubbles of gas, zinc disappears, colourless solution formed
Zn(s) + 2HCl(aq) → ZnCl2(aq) + H2(g)
Zn(s) + H2SO4(aq) → ZnSO4(aq) + H2(g)
iron
bubbles of gas, iron disappears, pale-green solution formed
Fe(s) + 2HCl(aq) → FeCl2(aq) + H2(g)
Fe(s) + H2SO4(aq) → FeSO4(aq) + H2(g)
metal + acid → a metal salt + hydrogen
Metal displacement reactions
Displacement reaction: a reaction in which a more reactive element displaces a less reactive element from a solution of its salt
Displacement as a redox reaction
• oxidation is the loss of electrons
• reduction is the gain of electrons.
An overview of metal reactivity
K -> Na -> Ca -> Mg -> Al -> (C) -> Zn -> Fe -> (H) -> Cu -> Ag -> Au
The most reactive metals are the most powerful reducing agents, giving electrons to other ions or compounds.