导图社区 Step Polymerization
MMC equations (the underlying logic in dynamic research) for step polymerization, take the polyester reaction as an example.
MMC equations (the underlying logic in dynamic research) for chain polymerization, provide guidance for polymer synthesis.
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MMC equations
Law of mass action
• 0.1<K<10, symmetry mechanism • Single molecule reaction balances instantly • The positive and negative reaction rates at a certain moment do not affect each other
Simultaneous
Material conservation
[COOH]=[OH]
Material characteristics
specific materials
body molecule
[COOH]=[OH] , linear molecule
f=2
(positive)
(negative)
solve
closed
self-catalyzed
0.8<p<0.95
p<0.8
added acid
decisive step
quasi-equilibrium