导图社区 IBDP 化学 第三章思维导图
Chapter3 Periodicity Mindmap,主要内容包括big picture。Periodic table structure.Periodic trend.
编辑于2023-02-08 21:51:23 上海U3. Periodicity
Big Picture
Periodic Table Structure
Periodic Trend
3.1 Periodic Table Structure
Atomic number
Elements in the periodic table are arranged in order of increasing nuclear charge
Atomic Number Z = Proton number, electron number = The order of the table
Groups and periods
Groups: vertical direction; period: horizontal direction
Elements in the same group share similar chemical properties, and shows a similar trends in their chemical properties.
As you move across the periods, changes in the chemical and physical properties are repeated in the next period.
Group number is equal to the valence electron number
The period number gives the number of occupied main energy levels in the atom.
Electron configuration
4 big orbitals: s, p, d, f
The s-block elements occupy groups 1 and 2.
Elements in group 13 to 18 are p-block elements.
The d-block consists of the elements in group 3 to 12.
Elements in the f-block are found at the lanthanides and actinides
Note: ll electrons in the highest occupied main energy level of an atom (the valence shell) are considered to be valence electrons, even though they may be in different sub-levels.
Note: Each single orbital can be filled max. 2 electrons, the electrons will fill each orbital 1 electron first and then fill the second one after all the orbitals have 1 electron.
The filling order: 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, ...
Identical groups
Group 1: The alkali metals
The most reactive group of metals – react strongly with cold water.
Example reaction formula: 2Na+2H2O=2NaOH+H2
Group 17: Halogens
The most reactive group of non-metals.
Example reaction formula: 2NaBr+Cl2=2NaCl+2Br
Group 18: Noble gas
A group of very unreactive monatomic gases.
Stable structure with all shells fulled
Transition metals
d-orbital elements
Cu configuration: 3d10*
Relatively stable metals with only moderate reactivity – useful for construction.
3.2 Periodic Trend
Periodic table trend
Electron affinity increase as go up (and go across) the table
Reason 1: Smaller atomic radius
Reason 2: Net charge increase (Only for go up), charge increase
Reason 3: Weak blocking effect
Reason 4 (Only for across): Same shell but less shielding effect
Reason 5 (Only for go up): Less shells
Electronegativity increase as go up (and go across) the table
Reason 1: Radius decrease
Reason 2: Nuclear charge increase, and net charge increase (Only for go up)
Reason 3: Attraction increase between electrons and nucleus
Reason 4 (Only for across): Same shell but less shielding effect
Atomic radius, ionic radius decrease as go up (and go across) the table
Number of shells are the same (or less), and the nucleus charge increase
Ionization energy increase as go up (and go across) the table
Reason 1: Number of inner electron shells
Reason 2: Charge on the nucleus increase
Reason 3: Atomic radius increase
Melting points increase as go across the group 1, 2, 13, and 14 Decrease as go across the group 18, 17, 16, 15
Influenced by: intermolecular forces, strength of bonding, or nature of bonding
Trends Oxides across period
Acid-Base character
Basic:Na2O(s), MgO(s)
Na2O+H2O=2NaOH
MgO+H2O=Mg(OH)2
MgO+2HCl=MgCl2+H2O
Amphoteric: Al2O3 (s)
Al2O3+3H2SO4=Al2(SO4)3+3H2O
Al2O3+3H2O+2OH(-) =2Al(OH)4(-)
Al2O3+6H(+)=2Al(3+)+3H2O
Acidic: SiO2(s), P4O10(s)/P4O6(s), SO3(l)/SO2(g), Cl2O7(l)/Cl2)(g)
SO2+H2O=H2SO3
SO3+H2O=H2SO4
P4O6+6H2O=4H3PO3
P4O10+6H2O=4H3PO4
Cl2O7+H2O=2HClO4
Cl2O+H2O=2HClO
SiO2+2OH(-)=SiO3(2-)+H2O
Structure
Giant Ionic with strong electrostatic forces: Na2O, MgO, Al2O3
Giant Covalent between atoms: SiO2
Molecular Covalent with Van Der Vaals: P4O10/P4O6, SO3/SO2, Cl2O7/Cl2O
Trends for Group 1
Physical properties
Good conductors of electricity and heat
Low densities
Gray shiny surfaces
Chemical properties
Reactive
Form ionic compounds with non-metals
Reactivity and intensity order: Li<Na<K<Rb<Cs
Reason 1: As go down more outershells
Reason 2: Atomic radius increase
Reason 3: Blocking effect
Reason 4: The net charge growth is negative, which lead to weaker attraction
Reaction with water
Release hydrogen
Li: Merely no reaction
2Li+2H2O=2LiOH+H2
Na: Heat is produced
2Na+2H2O=2NaOH+H2
K: Ignite with a lilac flame
2K+2H2O=2KOH+H2
Trends for Group 17
Halide ion test
Cl(-): White precipitate (AgCl)
2Ag+2HCl=2AgCl+H2
Br(-): Cream precipitate (AgBr)
2Ag+2HBr=2BrCl+H2
I(-): Yellow precipitate (AgI)
2Ag+2HI=2AgI+H2
Reactivity order: At<I<Br<Cl<F
Reason 1: Atomic radius increase
Reason 2: Shielding effects