Syllabus of the Thermaldynamic

热力学大纲Syllabus of the Thermaldynamics:：basic concepts、First law of thermodynamic.、Second law of thermodynamic.

Syllabus of the Thermaldynamics

• basic concepts
  • specific weight
  • Specifit Heats
    • cv
      • du=cv*dt
    • cp
      • dh=cp*t
      • cp=cv+R
  • systems and control volumes
    • system
      • closed
        • 与外界没有质量交换的系统
      • moved
    • surroundings
    • boundary
      • fixed
      • movable
  • Forms of energy
    • total energy E
    • internal energy U
      • The sum of all the microscopic of energy
    • Mechanical energy
      • Kinetic energy, KE
      • Potential energy, PE
    • E=U+KE+PE
  • energy transfer
    • heat
    • work
      • electrical
      • friction
• First law of thermodynamic.
  • Energy can neither be created nor destoyyed during a process; it can only change forms.
  • pure substance
    • fixed chemical compositon气态水和液态水的混合物也属于纯净物
  • phase-change
    • Compressed Liquid
    • Saturated liquid
    • Saturated liquid-vapor mixture
      • 
      • 
    • Saturated vapor
    • Superheated vapor
  • ENTHALPY
    • H=U+PV
  • 理想气体状态方程
    • 注意条件是只有气体才能用的方程。 不能用于R134A和Water。 特殊地，steam也会由气体常数，是可以用这个方程的。
    • PV = (Z)RT
      • Compressibility
  • Moving boundary work
    • Isothermal
      • 再Moving boundary work中只有等温变化的情况。
      • 等温，体积是变化量
        • Wb=mRTln（V2/V1）
  • specific heats
    • energy balance
    • enthalpy
• Second law of thermodynamic
  • Heat will not transfer spontaneously from low temperature to high temperature.
  • reversibility-Carnot cycle.
  • entropy
    • isentropic processes
  • Gas power cycles
    • Otto
    • Diesel
  • Vapor power cycle
    • Rankine cycle
  • Mass&energy control volumes